Volume 2 | Issue 1 | Year 2011 | Article Id. IJMTT-V2I1P505 | DOI : https://doi.org/10.14445/22315373/IJMTT-V2I1P505
Various low cost sorbents have been used for removal of toxic metals from aqueous solution for the treatment of Cr (III) and Cr (VI) containing waste water using agricultural wastes. Artificial Neural Network (ANN) was applied to sorption batch studies to develop and validate a model that can predict Cr (III) and Cr (VI) removal efficiency. Earlier investigations correlated the experimental data with available models or some modified empirical equations but these results were unable to predict the values of parameters from a single equation. ANN is effective in modeling and simulation of highly non linear multivariable relationships. A well designed network can converge even on multiple numbers of variables at a time without any complex modeling and empirical calculations. The prediction of removal of Cr (III) and Cr (VI) from waste water has been made using variables of metal concentration, biomass dosage, contact time and initial volume. Different types of the ANN architecture have been tested by varying the neuron number of entrance and the hidden layers, resulting into an excellent agreement between the experimental data and the predicted values. The data of one hundred eighty laboratory experimental sets were used for structuring single layer ANN model. Series of experiments resulted into the performance evaluation based on considering 20 % data for testing and 20 % data for cross validation at 3000 Epoch with 0.70 momentums. The Levenberg– Marquardt algorithm (LMA) was applied giving a minimum mean squared error (MSE) for training and cross validation.
[1] Gardea-Torresdey, J.L., Gonzalez, J.H., Tiemann, K.J., Rodriguez, O.,Gamez, G., . Phytofilteration of hazardous cadmium, chromium, lead, and zinc ions by biomass of Medicago sativa (alfalfa). J. Hazard.Mater, 57, 29–39, (1998).
[2] S.S. Ahluwalia and D. Goyal. Removal of heavy metals from waste tea leaves from aqueous solution, Eng Life Sci, 5, 158-162, (2005).
[3] Dhiraj Sud , Garima Mahajan, M.P. Kaur. Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions – A review. Bioresource Technol, 99, 6017–6027, (2008).
[4] Prakash N, Manikandan SA, Govindaranjan Vijayagopal V. Prediction of biosorption efficiency for the removal of copper (II) using artificial neural networks. J. Hazard.Mater,152, 1268- 1275, (2008).
[5] Y.-S. Park, T.S. Chon, I.S. Kwak, S. Lek. Hierarchical community classification and assessment of aquatic ecosystems using artificial neural networks. Science of the Total Environ, 327, 105–122, (2004).
[6] L. Belanche, J.J. Valdes, J. Comas, I.R. Roda, M. Poch. Prediction of the bulking phenomenon in wastewater treatment plants. Artif Intell Eng, 14, 307–317, (2000).
[7] G.R. Shetty, S. Chellam. Predicting membrane fouling during municipal drinking water nanofiltration using artificial neural Networks. J Membrane Sci, 217, 69–86, (2003).
[8] N. Delgraange, C. Cabassud, M. Cabassud, L. Durand-Boulier, J.M. Laine. Neural network for prediction of ultra filtration transmembrane pressure application to drinking water production. J Member Sci, 150, 111-123, (1998).
[9] K.A. Al-Shayji. Modeling simulation and optimization of large scale commercial Desalination plant, PhD thesis, Virginia Polytechnic Institute and State University, Virginia, USA 1998.
[10] D.R. Baughman, Y.A. Lieu. Neural network in bioprocessing and chemicalEngineering, Academic Press. San
Diego, 1995.
[11] P. Goyal, P. Sharma, S. Srivastava and
M.M Srivastava. Potential of Saraca
indica leaf powder (SILP) for chromium
removal from aqueous solution”, Arch.
Environ. Protec., 33 (2), 35-44, (2007).
[12] M.M. Srivastava, A. Chauhan and S.
Srivastava. Adsorption behavior of
cadmium and nickel from aqueous
solution by Saraca indica leaf powder.
Arch. Environ. Protect., 31, 57-68,
(2005).
[13] Kardam, A., Goyal, P., Arora, J.K., Raj,
K.R. and Srivastava, S.. Novel
biopolymeric material: Synthesis and
characterization for decontamination of
cadmium from waste water. National
Academy of Science letters, 32 (5-6),
179-181, (2009).
[14] Chu, K. H. and Kim, E. Y.. Predictive
modeling of competitive biosorption
equilibrium data, Biotechnology and
Bioprocess Engineering, 11, 67-71,
(2006).
[15] K. Yetilmezsoy and S. Demirel,
Artificial neural network (ANN)
approach for modeling of Pb (II)
adsorption from aqueous solution by
Antep Pistachio (Pistacia Vera L.)
shells, J Hazard Mat, Vol 153, pp.1288-
1300, (2007).
[16] M.A Hashem, Adsorption of lead ions
from aqueous solution by okra wastes,
International J Phys Sci, Vol 2 (7),
178-184, (2007
).
[17] N.T. Abdel-Ghani, and El-Chaghaby,
G.A.F, Influence of operating conditions
on the removal of Cu, Zn, Cd and Pb
ions from wastewater by adsorption. Int
J Environ Sci and Tech, 4 (4), 451-456,
(2007).
[18] N.T. Abdel-Ghani, M. Hefny and G.A.F
El-Chaghaby, Removal of lead from
aqueous solution using low cost
abundantly available adsorbents. Int J
Environ Sci and Tech, 4 (1), 67-73,
(2007).
Abhishek Kardam, Kumar Rohit Raj, Jyoti Kumar Arora ,Shalini Srivastava, "ANN MODELING ON PREDICTIONS OF BIOSORPTION EFFICIENCY OF ZEA MAYS FOR THE REMOVAL OF Cr (III) AND Cr (VI) FROM WASTE WATER," International Journal of Mathematics Trends and Technology (IJMTT), vol. 2, no. 1, pp. 23-29, 2011. Crossref, https://doi.org/10.14445/22315373/IJMTT-V2I1P505